Publications

Metal-organodiphosphonate chemistry: Hydrothermal syntheses and structures of Ca(II) coordination polymers with xylyldiphosphonate ligands. Lopez-Diaz, V.; Pellizerri, T. M. S.; Lijewski, M. D.; Zubieta, J.; Ruhlandt-Senge, K.; Inorganica Chimica Acta, 2016, 441, 109-116.

Heavy alkaline-earth metal organometallic and metal organic chemistry: synthetic methods and properties. Torvisco, A.; Ruhlandt-Senge, K.; Topics in Organometallic Chemistry, 2013, 45(Alkaline-Earth Metal Compounds), 1-27.

M-F interactions and heterobimetallics: furthering the understanding of heterobimetallic stabilization. Buchanan, W. D.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2013, 19(32), 10708-10715.

Alkaline earth metal di- and triphenylmethanides: analysis of ion association modes. Guino-o, M. A.; Torvisco, A.; Teng, W.; Ruhlandt-Senge, K.; Inorganica Chimica Acta, 2012, 389, 122-130.

Synthesis and characterization of cyano-substituted carborane-based compounds. Molecular structure of [1-(4-C7H7)-12-(C5H3-3-(CN)-3,4-(CH3)2)-C2B10H10]. Taylor, J.; Vargas, W.; Torvisco, A.; Ruhlandt-Senge, K.; Spender, J. T.; Dalton Transactions, 2011, 40(40), 10585-10591.

S-block organometallics: analysis of ion-association and noncovalent interactinos on structure and function in benzyl-based compounds. Torvisco, A.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2011, 50(24), 12223-12240.

Ligand and coligand effects on ion association in magnesium amides. Torvisco, A.; Ruhlandt-Senge, K.; Organometallics, 2011, 30(5), 986-991.

Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}. Rosado, P. J.; Ruhlandt-Senge, K.; Journal of Coordination Chemistry, 2011, 64(1), 186-193.

Advances in alkaline earth-nitrogen chemistry. Torvisco, A.; O’Brien, A. Y.; Ruhlandt-Senge, K.; Coordination Chemistry Reviews, 2011, 255(11-12), 1268-1292.

Electronic coupling in diiron complexes with the butadienediyl-bridged chain. Sponsler, M. B.; Englich, U.; Ruhlandt, K.; Jung, S.-C.; Ahn, H. G.; Chung, M.-C.; Journal of Nanoscience and Nanotechnology, 2011, 11(2) 1534-1537.

Highly volatile alkaline earth metal fluoroalkoxides. Buchanan, W. D.; Guino-o, M. A.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2010, 49(15), 7144-7155.

Synthesis and stabilization-advances in organoalkaline earth metal chemistry. Buchanan, W. D.; Allis, D. G.; Ruhlandt-Senge, K.; Chemical Communications, 2010, 46(25), 4449-4465.

π-Coordination as a structure determining principle: structural characterization of [K(Odpp)] and {[K2(Odpp)2H2O]2}. Buchanan, W. D.; Nagle, E. D.; Ruhlandt-Senge, K.; Main Group Chemistry, 2009, 8(4), 263-273.

When VSEPR fails: experimental and theoretical investigations of the behavior of alkaline-earth-metal acetylides. Guino-o, M.; Alexander, J. S.; McKee, M. L.; Hope, H.; Englich, U. B.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2009, 15(44), 11842-11852, S11842/1-S11842/8.

Metal based synthetic routes to heavy alkaline earth aryloxo complexes involving ligands of moderate steric bulk. Deacon, G. B.; Jung, P. C.; Moxey, G. J.; Guino-o, M.; Ruhlandt-Senge, K.; Dalton Transactions, 2009, (25), 4878-4887.

Ion association trends in alkaline earth-metal tetraphenylborates. Verma, A.; Guino-o, M; Gillett-Kunnath, M.; Teng, W.; Ruhlandt-Senge, K.; Zeitschrift fuer Anorganische und Allgemeine Chemie, 2009, 635(6-7), 903-913.

Charge-separated and molecular heterobimetallic rare earth-rare earth and alkaline earth-rare earth aryloxo complexes featuring intramolecular metal-π-arene interactions. Chemistry- A European Journal, 2009, 15(22), 5503-5519, S5503/1-S5503/15.

The supramolecular architecture of arene complexes of bis(polyfluorophenyl)mercurials. Deacon, G. B.; Forsyth, C. M.; Jung, P. C.; Ness, T. J.; Izgorodina, E.; Baldamus, J.; Meyer, G.; Patenburg, I.; Hitzbleck, J.; Ruhlandt-Senge, K.; European Journal of Inorganic Chemistry, 2008, (30), 4770-4780.

BiPh3-A convenient synthon for heavy alkaline-earth metal amides. Gillett-Kunnath, M. M.; MacLellan, J. G.; Forsynth, C. M.; Andrews, P. C.; Deacon, G. B.; Ruhlandt-Senge, K.; Chemical Communications, 2008, (37), 4490-4492.

Developments in heterobimetallic s-block systems: synthesis and structural survey of molecular M/Ae (M= Li, Na, K, Cs; Ae= Ca, Sr) aryloxo complexes. Zuniga, M. F.; Deacon, G. B.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2008, 47(11), 4669-4681.

More than steric effects: unlocking the coordination chemistry of barium pyrazolates. O’Brien, A. Y.; Hitzbleck, J.; Torvisco, A.; Deacon, G. B.; Ruhlandt-Senge, K.; European Journal of Inorganic Chemistry, 2008, (1), 172-182.

A unique hetrobimetallic benzyl calciate-an organometallic mixed-metal species involving a heavy alkaline-earth metal. Guino-o, M. A.; Campana, C. F.; Ruhlandt-Senge, K.; Chemical Communications, 2008, (14), 1692-1694.

Porphyrin complexes containing coordinated BOB groups: synthesis, chemical reactivity and the structure of [BOB(tpClpp)]2+. Belcher, W. J.; Hodgson, M. C.; Sumida, K.; Torvisco, A.; Ruhlandt-Senge, K.; Ware, D. C.; Boyd, P. D. W.; Brothers, P J.; Dalton Transactions, 2008, (12), 1602-1614.

The metal influence on the structural chemistry of alkynes: synthetic, spectroscopic and structural studies on magnesium acetylides. Guino-o, M. A.; Baker, E.; Ruhlandt-Senge, K.; Journal of Coordination Chemistry, 2008, 61(1), 125-136.

Alkali metal diphenylmethanides: synthetic, computational and structural studies. Alexander, J. S.; Allis, D. G.; Teng, W.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2007, 13(35), 9899-9911.

Lithium aryloxo magnesiates: an examination of ligand size and donor effects. Zuniga, M. F.; Kreutzer, J.; Teng, W.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2007, 46(24), 10400-10409.

New structural features in heavy alkaline earth-meta chemistry- molecular heterobimetallic group 1, Ba complexes. Zuniga, M. F.; Deacon, G. B.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2007, 13(7), 1921-1928.

Structural trends in alkaline earth and rare earth metal 3,5-diisopropylpyrazolates. Hitzbleck, J.; Deacon, G. B.; Ruhandt-Senge, K.; European Journal of Inorganic Chemistry, 2007, (4), 592-601.

Synthetic, structural, and theoretical invetigations of alkali metal germanium hydrides- contact moleculars and separated ions. Teng, W.; Allis, D. G.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2007, 13(4), 1309-1319.

Temperature-dependent coordination of phosphine to five-coordinate alkenylruthenium complexes. Seetharaman, S. K.; Chung, M.-C.; Englich, U.; Ruhlandt-Senge, K.; Sponsler, M. B.; Inorganic Chemistry, 2007, 46(2), 561-567.

Role of donor and secondary interactions in the structures and thermal properties of alkaline-earth and rare-earth metal pyrazolates. Hitzbleck, J.; O’Brien, A. Y.; Deacon, G. B.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2006, 45(25), 10329-10337.

From monomers to solids: controlled hydrolysis to form novel, heteroleptic hydroxide-containing complexes. Teng, W.; Guino-o, M.; Hitzbleck, J.; Englich, U.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2006, 45(23), 9531-9539.

Influence of the steric demand of the 2,4,6-trialkylphenyl substituents on the structures and reactivity of diarylzinc. Westerhausen, M.; Ossberger, M. W.; Alexander, J. S.; Ruhlandt-Senge, K.; Zeitschrift fuer Anorganische und Allgemeine Chemie, 2005, 631(13-14), 2836-2841.

Pyridine-ring alkylation of cytotoxic r-1,c-3,c-5-tris[(2-pyridylmethyl)amino]cyclohexane chelators: structural and electronic properties of the MnII, FeII, NiII, CuII and ZnII complexes. Childers, M. L.; Su, F.; Przborowska, A. M.; Bishwokarma, B.; Park, G.; Brechbiel, M. W.; Torti, S. V.; Torti, F. M.; Alexander, J. S.; Rogers, R. D.; Ruhlandt-Senge, K.; Planalp, R. P.; European Journal of Inorganic Chemistry, 2005, (19), 3971-3982.

Synthesis and structures of monomeric magnesium, calcium, strontium, and barium amides involving the N,N-(2,4,6-trimethylphenyl)(trimethylsilyl)amido ligand. Gillett-Kunnath, M.; Teng, W.; Vargas, W.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2005, 44(13), 4862-4870.

Syntheses and structures of the first heavy-alkali-metal tris(trimethylsilyl)germanides. Teng, W.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2005, 11(8), 2462-2470.

Linear finite “Mers” – homoleptic polynuclear heavy alkaline earth metal pyrazolates. Hitzbleck, J.; Deacon, G. B.; Ruhlandt-Senge, K.; Angewandte Chemie, International Edition, 2004, 43(39), 5218-5220.

Heavy alkaline earth metal pyrazolates: synthetic pathways, structural trends, and comparison with divalent lanthanoids. Hitzbleck, J.; O’Brien, A. Y.; Forsyth, C. M.; Deacon, G. B.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2004, 10(13), 3315-3323.

Syntheses and structures of the first heavy alkaline earth metal bis(tris(trimethylsilyl))silanides. Teng, W.; Ruhlandt-Senge, K.; Organometallics, 2004, 23(11), 2694-2700.

More arrows in the quiver: new pathways and old problems with heavy alkaline earth metal diphenylmethanides. Alexander, J. S.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2004, 10(5), 1274-1280.

Syntheses and structures of the first heavy alkaline earth metal germanides M(THF)n(Ge(SiMe3)3)2 (M=Ca, n=3; M=Sr, n=3; and M=Ba, N=4). Teng, W.; Ruhlandt-Senge, K.; Organometallics, 2004, 23(5), 952-956.

Synthesis and reactivity of novel alkali metal stannides. Schollmeier, T.; English, U.; Fischer, R.; Prass, I.; Ruhlandt, K.; Schuermann, M.; Uhlig, F.; Zeitschrift fuer Naturforschung, B: Chemical Sciences, 2004, 59(11/12), 1462-1470.

An examination of metal-ligand binding modes in rubidium diphenylmethanide. Alexander, J. S.; Allis, D. G.; Hudson, B. S.; Ruhlandt-Senge, K.; Journal of the American Chemical Society, 2003, 125(49), 15002-15003.

Synthesis and preparation of alkaline-earth-metal triphenylmethanides M(CPh3)2(18-crown-6)(HMPA)2 and the ether scission products [M(C12H23O6)(N(SiMe3)2)]2 (M=Sr, Ba). Alexander, J. S.; Ruhlandt-Senge, K.; Hope, H.; Organometallics, 2003, 22(24), 4933-4937.

Synthesis, structures and characterization of the calcium pyrrolates [Ca{2-(dimethylaminomethyl)pyrrolyl}2 donorn] (donor=THF and pyridine, n=2; DME and TMEDA, n=1) as potential precursors for solid-state applications. Vargas, W.; Ruhlandt-Senge, K.; European Journal of Inorganic Chemistry, 2003, (18), 3472-3479.

Syntheses and structures of barium silanides: contact and separated ions. Teng, W.; Englich, U.; Ruhlandt-Senge, K.; Angewandte Chemie, International Edition, 2003, 42(31), 3661-3664.

Meso-substituted aromatic 34n core-modified octaphyrins: syntheses, characterization and anion binding properties. Anan, V. G.; Venkatraman, S.; Rath, H.; Chandrashekar, T. K.; Teng, W.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2003, 9(10), 2282-2290.

Syntheses and structures of magnesium pyridine thiolates-model compounds for magnesium binding in photosystem I. Pedrares, A. S.; Teng, W.; Ruhlandt-Senge, K.; Chemistry- A European Journal, 2003, 9(9), 2019-2024.

The synthesis and characterization of two new 19-vertex metallaborane clusters: [B18H20Ni(η5-C5H5)]-1 and [B18H19(2-THF)Ni(η5-C5H5)]. Taylor, J. W.; English, U.; Ruhlandt, K.; Spencer, J. T.; Inorganic Chemistry Communications, 2002, 5(4), 274-277.

Not just heavy “Grignards”: recent advances in the organometallic chemistry of the alkaline earth metals calcium, strontium and barium. Alexander, J. S.; Ruhlandt-Senge, K.; European Journal of Inorganic Chemistry, 2002, (11), 2761-2774.

A novel group of alkaline earth metal amides: syntheses and characterization of M[N(2,6-iPr2C6H3)]2(THF)2 (M=Mg, Ca, Sr, Ba) and the linear, two-coordinate Mg[N(2,6-iPr2C6H3)(SiMe3)]2. Vargas, W.; Englich, U.; Ruhlandt-Senge, K.; Inorganic Chemistry, 2002, 41(21), 5602-5608.

Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B18H22 borane cluster: molecular structures of [Ni(THF)4(H2O)2][B18H20Ni(η5-C5H5)]2 and [B18H19(2-THF)Ni(η5-C5H5)]. Taylor, J. W.; Englich, U.; Ruhlandt-Senge, K.; Spender, J. T.; Journal of the Chemical Society, Dalton Transactions, 2002, (17), 3392-3397.

Synthesis and reactivity of stannyloligosilanes IV [1]: from hydrido substituted stannasilanes towards stannasiloxanes. Englich, U.; Prass, I.; Ruhlandt-Senge, K.; Schollmeier, T.; Uhlig, F.; Monatshefte fuer Chemie, 2002, 133(7), 931-943.

Preparation and characterization of macropolyhedral metallaborane clusters from the anti-B18H22 borane cluster: crystal structure of [(CH3)4N][anti-B18H20Co(CO)3]. Taylor, J. W.; Englich, U.; Ruhlandt-Senge, K.; Spencer, J. T.; Organometallics, 2002, 21(14), 3054-3057.